Yep, I THINK I know what the problem is:
I’ve been messing with installing Grub-Customizer. It use to work just fine; now ZIP!!
Starting with Fedora 30-something – and then with RHEL later – instead of putting the /boot/grub2/grub.cfg (can be viewed in /etc/grub.d/10_linux) like most everyone else does and allows Grub-Customizer to work, Red Hat has moved the boot files (?) to /boot/loader/entries, now grub.cfg only references where to look in order to boot ie. in /etc/grub.d/10_linux. In short it is looking in the WRONG Place. I was able to PROVE it too:
First I disconnected all my HDD’s and left only the NVMe drive that holds RL 8.5 in place. I then rebooted the machine even though the SSD that contains openSUSE 15.3 Leap , still popped up in the menu, even ough the drive itself was disconnected.
Next I ran:
grub2-mkconfig -o /boot/grub2/grub.cfg
and rebooted the machine. As expected the menu now only showed the 3 RL 8.5 entries.
Next I ran Grub Customizer expecting that the RL 8.5 entries would show up. THEY NEVER DID! Nor did openSUSE 15.3 since the cable to the SSD was still disconnected.
Next I re-connected all the cables and re-booted. I now still only had the Entries for RL 8.5.
Next I ran
grub2-mkconfig -o /boot/grub2/grub.cfg
and rebooted the machine. This time the menu now showed both the RL 8.5 Entries and the openSUSE 15.3 Leap Entries.
Finally I ran Grub-Customizer once again and this time the Grub-Customizer Menu was back and still referenced /etc/grub.d/30_os-prober as the drives where openSUSE 15.3 could be found. Rocky Linux 8.5 was still absent as was the case when I started.
CONCLUSION:
By moving the boot files (?) from /boot/grub2/grub.cfg which references to look in /boot/loader/entries, since there is no INTERNAL reference point that points where to look in the EXTERNAL DRIVE that tells the drive to look under /boot/loader/entries to find the the boot files (?), instead you come up with the drive being unable boot the RL 8.5.
The SOLUTION MAY be fairly simple… or complex.
One use an EXTERNAL drive and then mount the Rocky Linux /boot partition under /mnt. Use a file viewer such as Midnight Commander and go into /mnt and look for the RL 8.5 /boot partition then GoTo /boot => /loader => /entries and open it up and look inside. If there are files inside /entries then you can PROBABLY get RL up and running; if /entries is EMPTY you have TROUBLES!!
ASSUMING that there are boot files (?) still in /boot/loader/entries the SOLUTION is to make the Rocky Linux 8.5 Menu the MASTER Menu. This will require that you run
grub2-mkconfig -o /boot/grub2/grub.cfg
any other OS or drive will be booted from the Rocky Linux 8.5 MASTER MENU. IF OTOH the Windows, or other OS holds the MASTER MENU, then RL is unlikely to boot if there is no pointer to look in /boot/loader/entries to boot RL 8.5