UEFI (firmware) does load something (bootloader) from some ESP (EFI System Partition).
What UEFI can load is within motherboard, not on any drive. Example:
efibootmgr -v | grep rocky
Boot0000* rocky HD(1,GPT,a1c36011-97a2-45e3-95d1-6c37965770f4,0x800,0x12c000)/File(\EFI\rocky\shimx64.efi)
Boot0001* rocky HD(1,GPT,d7797843-f2d4-40ae-b1c4-2b800d2ae59f,0x800,0x12c000)/File(\EFI\rocky\shimx64.efi)
This tells that there are two “UEFI boot entries” that would load Rocky’s GRUB.
Furthermore, they are on different partitions:
a1c36011-97a2-45e3-95d1-6c37965770f4
d7797843-f2d4-40ae-b1c4-2b800d2ae59f
IIRC, there are partition UUIDs, not filesystem UUIDs. Command blkid does show those, if the lsblk does not have option to show them.
Your UEFI finds a bootloader from the USB (“sdd1”). The UEFI might not have stored entry about it, nor look for vendor-specific *.efi, but it does look for certain “usual suspects” from drives, which Rocky install may have populated too.
If you now make a copy of the ESP from USB to another drive, you have to create an UEFI entry that does point to the shim64.efi on the new partition (with efibootmgr). Then make that the default entry (with efibootmgr or UEFI setup).
The \EFI\rocky\grub.cfg is merely a wrapper that includes grub2/grub.cfg from the partition that has /boot based on UUID. Hence, you have to update that UUID in that wrapper, if you want to use different partition (a copy of “sdd2” on regular drive).
Since partitions and filesystems are referred to with their UUIDs, you cannot simply clone partitions. You have to make the UUID’s unique.
LVM is both more complex and more flexible than “plain” partitions. One could make a partition on drive a PV, add it to the VG “rl_mareba”, and then pvmove extents of LVs from the PV on USB (“sdd3”) to the other PV.
Alas, your USB is 1TB and the other drives are 500GB models with who-knows-what on them. A LV can span multiple PV, but I bet there aint space for the 836.3G LV. The default filesystem used by Rocky is XFS and it is not possible to shrink an existing XFS volume.